Reply to the comment on "Sensitive marker bands for the detection of spin states of heme in surface-enhanced resonance Raman scattering spectra of metmyoglobin".
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چکیده
In our SERRS spectra of metmyoglobin by excitation at 514 nm, the peak at 1510 cm(-1), which is assigned to the 6-coordinated heme in the low spin state, was observed by the addition of imidazole and NaN3. Thus, the SERRS likely originates not from the non-native 5-coordinated heme, which is in the high spin state.
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عنوان ژورنال:
- The Analyst
دوره 139 24 شماره
صفحات -
تاریخ انتشار 2014